The SCS values used for the calculations are taken from [1].
Better estimations are available for the chemical shifts of carboxylic acids and esters and amides.
Literature
[1] "Parameter set for the prediction of the 13C-NMR chemical shifts of sp2- and sp-hybridized carbon atoms in organic compounds"Pretsch E, Fürst A, Robien W Anal. Chim. Acta 248 (1991) 415-428