Chemical shifts of the aldoses

	1	2	3	4	5	6		CH₃	CO	OCH₃

α-D-Galactopyranose	93.18	69.35	70.13	70.28	71.30	62.04
α-D-Galactopyranose	5.22	3.78	3.81	3.95	4.03	3.69	3.69

Methyl α-D-galactopyranoside	100.35	69.17	70.46	70.19	71.54	62.06				55.96
Methyl α-D-galactopyranoside	4.85	3.84	3.81	3.99	3.89	3.76	3.76			3.43

β-D-Galactopyranose	97.37	72.96	73.78	69.69	75.93	61.84
β-D-Galactopyranose	4.53	3.45	3.59	3.89	3.65	3.64	3.72

Methyl β-D-galactopyranoside	104.72	71.64	73.79	69.62	75.92	61.84				57.88
Methyl β-D-galactopyranoside	4.31	3.52	3.64	3.93	3.68	3.78	3.78			3.58

α-D-Galacturonic acid	93.07	69.03	70.26	71.64	72.30	176.43
α-D-Galacturonic acid	5.30	3.83	3.92	4.29	4.39

β-D-Galacturonic acid	96.89	72.62	73.79	71.18	76.44	175.59
β-D-Galacturonic acid	4.56	3.51	3.69	4.23	4.03

2-Acetamido-2-deoxy-α-D-galactopyranose	91.95	51.16	68.40	69.56	71.36	62.11		22.91	175.43
2-Acetamido-2-deoxy-α-D-galactopyranose	5.28	4.19	3.95	4.05	4.13	3.79	3.79	2.06

2-Acetamido-2-deoxy-β-D-galactopyranose	96.29	54.80	72.01	68.85	75.98	61.89		23.12	175.78
2-Acetamido-2-deoxy-β-D-galactopyranose	4.68	3.90	3.77	3.98	3.72	3.82	3.84	2.06

α-D-Glucopyranose	92.99	72.47	73.78	70.71	72.37	61.84
α-D-Glucopyranose	5.23	3.54	3.72	3.42	3.84	3.76	3.84

Methyl α-D-glucopyranoside	100.19	72.23	74.10	70.68	72.52	61.67				55.93
Methyl α-D-glucopyranoside	4.81	3.56	3.68	3.41	3.64	3.76	3.87			3.43

β-D-Glucopyranose	96.84	75.20	76.76	70.71	76.76	61.84
β-D-Glucopyranose	4.64	3.25	3.50	3.42	3.46	3.72	3.90

Methyl β-D-glucopyranoside	104.13	73.99	76.78	70.69	76.78	61.82				57.88
Methyl β-D-glucopyranoside	4.37	3.28	3.50	3.40	3.46	3.74	3.92			3.58

α-D-Glucuronic acid	92.96	72.26	73.52	72.91	72.47	177.42
α-D-Glucuronic acid	5.24	3.59	3.75	3.53	4.09

β-D-Glucuronic acid	96.77	75.00	76.53	72.69	76.93	176.47
β-D-Glucuronic acid	4.65	3.30	3.52	3.54	3.72

2-Acetamido-2-deoxy-α-D-glucopyranose	91.77	55.00	71.74	71.26	72.51	61.78		22.87	175.13
2-Acetamido-2-deoxy-α-D-glucopyranose	5.21	3.88	3.75	3.49	3.86	3.77	3.85	2.06

2-Acetamido-2-deoxy-β-D-glucopyranose	95.85	57.86	74.81	71.06	76.82	61.85		23.10	175.49
2-Acetamido-2-deoxy-β-D-glucopyranose	4.72	3.65	3.56	3.46	3.46	3.75	3.91	2.06

α-D-Mannopyranose	94.94	71.69	71.25	67.94	73.34	61.99
α-D-Mannopyranose	5.18	3.94	3.86	3.68	3.82	3.74	3.86

Methyl α-D-mannopyranoside	101.75	70.85	71.56	67.79	73.45	61.92				55.55
Methyl α-D-mannopyranoside	4.77	3.94	3.77	3.67	3.61	3.78	3.90			3.42

β-D-Mannopyranose	94.55	72.13	74.03	67.69	77.00	61.99
β-D-Mannopyranose	4.89	3.95	3.66	3.60	3.38	3.75	3.91

α-D-Mannuronic acid	94.80	71.42	71.10	69.95	73.68	177.58
α-D-Mannuronic acid	5.22	3.90	3.87	3.83	4.04

β-D-Mannuronic acid	94.48	71.93	73.86	69.58	76.95	176.82
β-D-Mannuronic acid	4.89	3.93	3.66	3.72	3.63

2-Acetamido-2-deoxy-α-D-mannopyranose	93.96	54.14	69.75	67.93	73.00	61.54		22.84	175.43
2-Acetamido-2-deoxy-α-D-mannopyranose	5.13	4.31	4.07	3.63	3.68	3.84	3.84	2.10

2-Acetamido-2-deoxy-β-D-mannopyranose	93.91	54.94	73.00	67.65	77.25	61.54		22.98	176.39
2-Acetamido-2-deoxy-β-D-mannopyranose	5.01	4.45	3.83	3.52	3.45	3.81	3.90	2.06

α-L-Fucopyranose	93.12	69.09	70.30	72.80	67.10	16.33
α-L-Fucopyranose	5.20	3.77	3.86	3.81	4.20	1.21

β-L-Fucopyranose	97.15	72.73	73.93	72.35	71.64	16.33
β-L-Fucopyranose	4.55	3.46	3.63	3.74	3.79	1.26

α-L-Rhamnopyranose	94.84	71.81	71.00	73.19	69.12	17.67
α-L-Rhamnopyranose	5.12	3.92	3.81	3.45	3.86	1.28

β-L-Rhamnopyranose	94.37	72.23	73.76	72.83	72.83	17.61
β-L-Rhamnopyranose	4.85	3.93	3.59	3.38	3.39	1.30

A practical guide to structural analysis of carbohydrates

Chemical shifts of the aldoses