For GLC-MS a Varian MAT 311 gas chromatograph mass spectrometer - Spectro system SS-100
was used. For GLC an OV-225 packed column (200 cm X 2.0 mm) with a flow of 15-20 mL
He/min was used. The oven tempoerature was programmed between 170°-200°C
(2°C/min) and injector and interface were around 210°C. MS conditions uesd were:
ionization potential 70 eV, acceleration voltage 3 kV, emission current 1000 µA,
ion source temperature 160°C. Computer conditions used were: exponential scan speed 4 sec/decade. Sampling rate 6 kHz.
Mass spectra are presented in the following order:
glycerol triacetate
tetritol tetraacetate
pentitol pentaacetate
hexitol hexaacetate
6-deoxyhexitol pentaacetate
2,5-anhydrohexitol tetraacetate
3,6-dideoxyhexitol tetraacetate
heptitol heptaacetate
2-deoxyheptitol hexaacetate
1,3,4,5-tetra-O-acetyl-2-O-methylpentitol
1,2,4,5-tetra-O-acetyl-3-O-methylpentitol
1,2,3,4-tetra-O-acetyl-5-O-methylpentitol
1,4,5-tri-O-acetyl-2,3-di-O-methylpentitol
1,3,5-tri-O-acetyl-2,4-di-O-methylpentitol
1,2,4-tri-O-acetyl-3,5-di-O-methylpentitol
1,5-di-O-acetyl-2,3,4-tri-O-methylpentitol
1,4-di-O-acetyl-2,3,5-tri-O-methylpentitol
1,3,4,5,6-penta-O-acetyl-2-O-methylhexitol
1,2,4,5,6-penta-O-acetyl-3-O-methylhexitol
1,2,3,4,5-penta-O-acetyl-6-O-methylhexitol
1,4,5,6-tetra-O-acetyl-2,3-di-O-methylhexitol
1,3,5,6-tetra-O-acetyl-2,4-di-O-methylhexitol
1,3,4,5-tetra-O-acetyl-2,6-di-O-methylhexitol
1,2,5,6-tetra-O-acetyl-3,4-di-O-methylhexitol
1,2,4,5-tetra-O-acetyl-3,6-di-O-methylhexitol
1,2,3,5-tetra-O-acetyl-4,6-di-O-methylhexitol
1,5,6-tri-O-acetyl-2,3,4-tri-O-methylhexitol
1,4,6-tri-O-acetyl-2,3,5-tri-O-methylhexitol
1,4,5-tri-O-acetyl-2,3,6-tri-O-methylhexitol
1,3,5-tri-O-acetyl-2,4,6-tri-O-methylhexitol
1,2,5-tri-O-acetyl-3,4,6-tri-O-methylhexitol
2,5-di-O-acetyl-1,3,4,6-tetra-O-methylhexitol
1,5-di-O-acetyl-2,3,4,6-tetra-O-methylhexitol
1,4-di-O-acetyl-2,3,5,6-tetra-O-methylhexitol
1,3,4,5-tetra-O-acetyl-6-deoxy-2-O-methylhexitol
1,2,4,5-tetra-O-acetyl-6-deoxy-3-O-methylhexitol
1,2,3,5-tetra-O-acetyl-6-deoxy-4-O-methylhexitol
1,4,5-tri-O-acetyl-6-deoxy-2,3-di-O-methylhexitol
1,3,5-tri-O-acetyl-6-deoxy-2,4-di-O-methylhexitol
1,2,5-tri-O-acetyl-6-deoxy-3,4-di-O-methylhexitol
1,5-di-O-acetyl-6-deoxy-2,3,4-tri-O-methylhexitol
1,4-di-O-acetyl-6-deoxy-2,3,5-tri-O-methylhexitol
1,5-di-O-acetyl-3,6-dideoxy-2,4-di-O-methylhexitol
1,3,5,6-tetra-O-acetyl-2,4,7-tri-O-methylheptitol
1,4-di-O-acetyl-6-deoxy-2,3,5,7-tetra-O-methylheptitol
1,3,5-tri-O-acetyl-2,4,6,7-tetra-O-methylheptitol
Additional spectra:
2-deoxyhexitol pentaacetate
1,3,4,6-tetra-O-acetyl-2,5-di-O-methylhexitol
1,2,4-tri-O-acetyl-3,5,6-tri-O-methylhexitol
1,3,5,7-tetra-O-acetyl-2,4,6-tri-O-methylheptitol
1,3,4,5-tetra-O-acetyl-2,6,7-tri-O-methylheptitol
1,5,7-tri-O-acetyl-2,3,4,6-tetra-O-methylheptitol
1,2,5-tri-O-acetyl-3,4,6,7-tetra-O-methylheptitol
1,5-di-O-acetyl-2,3,4,6,7-penta-O-methylheptitol
|
|
::
::
::
Cite!